Physical
The assessment of the physical
properties of crude oils focuses on characteristics
such as viscosity, density and pour point
and how these change as oils weather at
sea.
The evaporative losses of oils during
weathering are also calculated, as is
the degree of emulsification that occurs.
Weathering is undertaken using a MacKay
Nadeau Steelman Tester (MNS), commonly
referred to as the ‘MacKay Tester.’
The time period that oils are weathered
for can range from an hour to upwards
of weeks.
The physical properties of crude oils,
and their character during the weathering
process can be used to assess the amenability
of the oils to various spill response
options and to particular items of response
equipment.
Chemical
Chemical characterisation can be
used to quantify the presence of toxic
hydrocarbons and other compounds present
in crude oils that could contribute to
the overall toxicity, and to fingerprint
the oil for future monitoring purposes.
A range of compounds can be examined including,
BTEX, polycyclic aromatic hydrocarbons
(PAHs), phenolics, paraffinic hydrocarbons
and sulphur compounds.
A range of biomarker compounds can be
determined, including a range of hopanes,
steranes, and isoprenoids. These compounds
are resistant to oil weathering processes
and are present in ratios which are characteristic
of particular oils. The quantification
of these compounds and the subsequent
calculation of the various biomarker ratios
effectively provide a ‘fingerprint’
of the oil. This can be of significant
value during post spill assessment work.
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